欲配制pH = 2.0和pH = 9.0的缓冲溶液,应分别选用( )。 化学式 K 1 K 2 K 3 H 3 PO 4 7.52 ́ 10 -3 6.23 ́ 10 -8 4.4 ́ 10 -13 H 2 CO 3 4.3 ́ 10 -7 5.6 ́ 10 -11 H 2 S 9.1 ́ 10 -8 1.1 ́ 10 -12 HCOOH 1.77 ́ 10 -4 HAc 1.76 ́ 10 -5 NH 3 · H 2 O 1.79 ́ 10 -5
A.
HCOOH - HCOONa和NaHCO 3 - Na 2 CO 3
B.
HAc - NaAc和NaH 2 PO 4 – Na 2 HPO 4
C.
HCOOH - HCOONa和NH 3 · H 2 O – NH 4 Cl
D.
HCl - NaCl和NaHCO 3 - Na 2 CO 3
E.
HAc - NaAc和NH 3 · H 2 O – NH 4 Cl