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【简答题】
(15分)氮的化合物在无机化工领域有着重要的地位。请回答下列问题: (1)基态氮原子的价电子排______。氮的最高价氧化物为无色晶体,它由两种离子构成:已知其阴离子构型为平面正三角形,则其阳离子的构型为 形,阳离子中氮的杂化轨道类型为 。 (2)某氮铝化合物X具有耐高温、抗冲击、导热性好等优良性质,广泛用于陶瓷工业等领域。工业上用氮气与氧化铝和碳在一定条件下反应生成X和CO,X的晶体结构如图所示,工业制备X的化学方程式为____。 (3)X晶体中包含的化学键类型为______。(填字母标号) A.离子键 B.共价键 C.配位键 D.金属键 (4)已知氮化硼与X晶体类型相同,且氮化硼的熔点比X高,可能的原因是______ (5)若X的密度为pg/cm 3 ,则晶体中最近的两个N原子的距离为______cm(加德罗常数用N A 表示,不必化简)。
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