称取2.200 g KHC2O4.H2C2O4.2H2O配制于250.mL容量瓶中,移取25.00 mL,用NaOH滴定消耗24.00 mL;移取25.00 mL,于酸性介质中用KMnO4滴定消耗30.00 mL,求此NaOH和KMnO4溶液的浓度。若用此KMnO4标准溶液测定样品中Fe含量,称取0.600 0 g样品消耗KMnO,21.00 mL,求算样品中Fe2O3的质量分数。
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