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(8分)铁氧体是一类磁性材料,通式为MO·xFe 2 O 3 (M为二价金属离子),如Fe 3 O 4 可表示为FeO·Fe 2 O 3 ,制备流程为: 根据题意回答: (1)现称取2.8 g铁粉,加入一定量的稀硫酸使其完全溶解后,再加入 g的FeCl 3 固体,经上述反应后,得到纯净的Fe 3 O 4 ; (2)如果以MgSO 4 和FeCl 3 为原料,要获得18.0克MgO·2Fe 2 O 3 ,在制取过程中至少需要1 mol/L的NaOH溶液 mL; (3)在一次制备Fe 3 O 4 的实验中,由于反应物比例控制不当,获得了另一种产品。取一定量该产品溶于足量盐酸中,还需通入标准状况下672 mLCl 2 才能把溶液中的Fe 2+ 全部氧化为Fe 3+ ,然后把所得溶液蒸干,灼烧至恒重,得9.6 g固体。该产品的化学式为 ; (4)有一种在电子工业上应用广泛的含铬铁氧体,其组成可表示为: ,现有15.2 g FeSO 4 ,经Cr 2 O 7 2- 、H 2 O 2 等物质处理后(不再引入含铁物质),可得到含铬铁氧体的质量范围为 。
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